Atmospheric carbon dioxide derives from multiple natural sources including volcanic out gassing, the combustion of organic matter such as decomposing trees and the respiration processes of living aerobic organisms.
Man-made sources of carbon dioxide come mainly from the burning of various fossil fuels, including diesel fuel.
The use of fossil fuel varies from country to country. However, figures taken from the UNFCCC reporting system for the Kyoto protocol for developed countries show that fossil fuel is mostly used for heating and power generation:

Source: UNFCCC
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While power generation and heating contribute to over 50% of the CO2 emissions, these are areas were viable alternate energy sources exist already today with low CO2 emissions.
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